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Jozi FM DJ Donald Sebolai suspected of murdering his girlfriend was scheduled to appear in the Protea Magistrate's Court in Soweto on Thursday.
A tip-off to police led to his arrest on Tuesday.
He had been on the run for a week.
Sebolai, a presenter at the Soweto-based community radio station was accused of stabbing his girlfriend several times in a flat in Jabulani, Soweto on June 29.
He apparently phoned the woman's friend and confessed to killing her, police said at the time.
A R50,000 reward had been offered for information leading to his arrest.